Tone
Context
Dear
Formal and polite
Standard, neutral greeting within the professional sphere.
Hello
Considered to be a standard greeting, more often used when the explicit purpose of your email is to introduce yourself to the recipient.
Hi
More casual and polite
Generally unacceptable for a business email, unless both you and the email recipient work in a more laid-back and relaxed industry.
Greetings to avoid:
Hey: Too casual for a business environment
Dear Sir or Madam/To whom it may concern: While tempting to use if you don’t know the person’s name, these phrases are overly formal and come across as too cold and impersonal.