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There are 5 main chemical reactions that occur: combination/synthesis, decomposition, single replacement, double replacement, and combustion. Recognizing the type of reaction that is occurring is as simple as looking at the given products and reactants in the chemical equation. Knowing the properties of each reaction will help you identify each one.

Method 1
Method 1 of 6:

Identifying Combination/Synthesis Reactions

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  1. A combination/synthesis reaction is aptly named because it is a reaction where 2 or more products combine together to form 1 new product. Remember that the reactants of an equation are always on the left side of the arrow. [1]
    • Many reactions have just 2 reactants, but you can have combination reactions with more than 2 reactants.
  2. As the name of the reaction indicates, the reactants must combine to form a new product. All products are found on the right side of the arrow. Very occasionally, there will be more than 1 product on the right side; however, most equations will only have 1 product. [2]
    • An example of a reaction resulting in 2 products: CO 2 + H 2 O --> C 6 H 12 O 6 + O 2
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  3. Examples are a great way to train yourself to recognize specific chemical reactions. The more examples you look at, the more likely you are to remember each type of reaction. [3]
    • Example 1: Cu + SO 4 --> CuSO 4
    • Example 2: CaO + CO 2 --> CaCO 3
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Method 2
Method 2 of 6:

Recognizing a Decomposition Reaction

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  1. A decomposition reaction is one where a reactant degrades or decomposes into its constituent parts. Energy, in the form of light, heat, or electricity, is usually the catalyst for the reaction. This type of reaction yields more products than reactants. Almost all basic decomposition reactions will have one reactant. [4]
    • The reactant is on the left side of the arrow.
  2. The reactant decomposes into multiple products. To recognize this type of reaction, just see if the equation resembles the general formula C --> A + B. Remember, the products are on the right side of the arrow. [5]
    • This reaction is the opposite of a combination reaction.
  3. Being able to recognize equations comes with practice. The more equations you look at, the easier it will be for you to immediately realize the reaction is decomposition. [6]
    • Example 1: 2H 2 O → 2H 2 + O 2
    • Example 2: KClO 3 --> KCl + O 2
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Method 3
Method 3 of 6:

Identifying a Single Replacement Reaction

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  1. A single replacement reaction occurs when one element replaces another element within a compound. It generally takes the form of AX + Y --> YX + A or A + XY --> XA + Y. One reactant is always a single element and the other reactant is always a compound. [7]
    • In a single replacement reaction either the anion (negatively charged ion) or the cation (positively charged ion) is replaced.
    • For example: Cu + AgNO 3 --> Ag + Cu(NO 3 ) 2 . In this example, copper (Cu) replaces the cation silver (Ag).
  2. When looking at the equation, you can easily tell if a single replacement has occurred if one of the elements has switched places into the new compound. Using the general formula as guidance, you can identify the reaction. [8]
    • For example: ZnS + O 2 --> ZnO + S
  3. Being able to quickly recognize a single replacement reaction takes time and practice. By looking at many different types of examples, you will improve your ability to identify this reaction without looking it up. [9]
    • Example 1: Fe + CuSO 4 → FeSO 4 + Cu. Iron replaces the copper element in the compound.
    • Example 2: Fe + HCl --> FeCl 3 + H 2 . Iron replaces the hydrogen.
    • Example 3: CaO + Al --> Al 2 O 3 + Ca. Aluminum replaces the calcium.
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Method 4
Method 4 of 6:

Recognizing a Double Replacement Reaction

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  1. These reactions are similar to single replacement reactions except that both components react and there are 2 replacements. The general formula is AB + XY --> AY + XB. The cations and anions from both compounds recombine to form 2 new compounds. [10]
    • These reactions are usually between acids and bases or metallic aqueous compounds.
    • For example: KOH + H 2 SO 4 --> K 2 SO 4 + H 2 O.
  2. When looking at an equation you can tell it is a double replacement reaction because the outside elements will recombine to make a new compound and the inside elements will recombine to make a new compound. The inside elements will switch position because the cation is always written first. [11]
    • For example: FeS + HCl --> FeCl 2 + H 2 S.
    • The outside elements, Fe and Cl, combine to form FeCl 2 .
    • The inside elements, S and H, switch positions and combine to form H 2 S.
  3. Looking at many examples of a double replacement reaction will help you recognize them when you see them on a quiz or test. The more examples you look at, the better you will be at identifying them. [12]
    • Example 1: NaCl + AgNO 3 → NaNO 3 + AgCl
    • Example 2: H 2 SO 4 + 2NaOH→ Na 2 SO 4 + 2H 2 O
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Method 5
Method 5 of 6:

Identifying a Combustion Reaction

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  1. On a most basic level, a combustion reaction is one where oxygen gas (O 2 ) reacts with anything to form carbon dioxide and water. Generally, the oxygen gas reacts with a compound of carbon and hydrogen. The combustion products are always CO 2 and H 2 O. [13]
    • The generic equation for a combustion reaction is: C x H y + O 2 --> CO 2 + H 2 O.
  2. The first step to identifying a combustion reaction is making sure that oxygen gas is 1 of the reactants. If there is no O 2 present, then the reaction is not combustion. [14]
    • For example: C 2 H 5 SH + O 2 --> CO 2 + H 2 O + SO 2 .
    • O 2 is reacting with a carbon-hydrogen compound so this reaction is probably a combustion reaction.
  3. When a combustion reaction occurs, the products will almost always contain CO 2 and H 2 O. If both carbon dioxide and water are not products of the reaction than combustion is not occurring. [15]
    • For example: C 2 H 5 SH + O 2 --> CO 2 + H 2 O + SO 2 .
    • Because CO 2 and H 2 O are both products, this reaction is an example of combustion.
  4. The more problems that you do, the easier it will be for you to recognize a combustion reaction when you come across it. With some practice, you'll be able to instantly identify a combustion reaction when you see one. [16]
    • Example 1: CH 4 + 2O 2 --> CO 2 + 2H 2 O
    • Example 2: C 2 H 5 OH + 3O 2 --> 2CO 2 + 3H 2 O
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Method 6
Method 6 of 6:

Recognizing a Reaction through Observation

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  1. Many synthesis and replacement (single and double) reactions are exothermic, meaning they release heat. Reactions that release a lot of heat, such as the thermite reaction, can be explosive. [17]
    • Take proper safety precautions when working with heat, such as wearing gloves and using eye protection.
    • The thermite reaction is a single-replacement reaction between iron (III) oxide and aluminum: [18] 3Fe 3 0 2 + 4Al → 2Al 2 0 3 + 6Fe
  2. Again, in many synthesis and replacement (single and double) reactions, a precipitate will form at the bottom of the tube. A precipitate is any solid material that is insoluble in water. [19]
    • Sodium chloride is the white powder formed when molten sodium burns in chlorine gas.
  3. Most decomposition reactions are endothermic meaning you need to add heat for the reaction to occur. If heat must be added, you may be observing a decomposition reaction. [20]
    • An example of a decomposition reaction is mercury (II) oxide decomposing into mercury metal and oxygen gas in the presence of heat: 2 HgO (s) + heat → 2 Hg (l) + O2 (g)
  4. Combustion reactions tend to explode, forming large amounts of light and heat energy. Oftentimes, this energy is released as fire. Combustion reactions are always exothermic, meaning they release heat. [21]
    • Some examples of combustion reactions are: hydrogen with oxygen, phosphorus with oxygen, and magnesium with oxygen.
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      1. https://www.khanacademy.org/science/chemistry/chemical-reactions-stoichiome/types-of-chemical-reactions/a/double-replacement-reactions
      2. https://chem.libretexts.org/Courses/Fullerton_College/Introductory_Chemistry_for_Allied_Health_(Chan)/06%3A_Introduction_to_Chemical_Reactions/6.05%3A_Types_of_Chemical_Reactions_-_Single_and_Double_Replacement_Reactions
      3. https://courses.lumenlearning.com/suny-introductory-chemistry/chapter/types-of-chemical-reactions-single-and-double-displacement-reactions/
      4. http://www.chemteam.info/Equations/Combustion.html
      5. https://chem.libretexts.org/Courses/Los_Angeles_Trade_Technical_College/Hybrid_Chem_51_v1/05%3A_Chemical_Reactions_and_Equations/4.4_Composition%2C_Decomposition%2C_and_Combustion_Reactions
      6. https://opentextbc.ca/introductorychemistry/chapter/composition-decomposition-and-combustion-reactions/
      7. http://2012books.lardbucket.org/books/beginning-chemistry/s08-04-composition-decomposition-and-.html
      8. https://flexbooks.ck12.org/cbook/ck-12-middle-school-physical-science-flexbook-2.0/section/5.23/primary/lesson/exothermic-reactions-ms-ps/
      9. https://www.enotes.com/topics/science/questions/reaction-between-iron-iii-oxide-aluminum-produce-462374
      10. https://pressbooks.bccampus.ca/chem1114langaracollege/chapter/4-2-classifying-chemical-reactions/
      11. https://flexbooks.ck12.org/cbook/ck-12-chemistry-flexbook-2.0/section/17.4/primary/lesson/endothermic-reactions-ms-ps/
      12. https://chem.libretexts.org/Bookshelves/Introductory_Chemistry/Introductory_Chemistry_(CK-12)/11%3A_Chemical_Reactions/11.06%3A_Combustion_Reactions

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