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On the atomic level, bond order is the number of bonded electron pairs between two atoms. In diatomic nitrogen (N≡N), for instance, the bond order is 3 because there are 3 chemical bonds linking the two nitrogen atoms. In molecular orbital theory, bond order is also defined as half of the difference between the number of bonding and antibonding electrons. For a straightforward answer: use this formula: Bond order = [(Number of electrons in bonding molecules) - (Number of electrons in antibonding molecules)]/2 .
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Know the formula. In molecular orbital theory, bond order is defined as half of the difference between the number of bonding and antibonding electrons. Bond order = [(Number of electrons in bonding molecules) - (Number of electrons in antibonding molecules)]/2 . [1] X Research source -
Know that the higher the bond order, the more stable the molecule. Each electron that entered a bonding molecular orbital will help stabilize the new molecule. [2] X Expert Source Chris Hasegawa, PhD
Retired Science Professor & Dean Expert Interview. 29 July 2021. Each electron that entered an antibonding molecular orbital will act to destabilize the new molecule. Note the new energy state as the bond order of the molecule.- If the bond order is zero, the molecule cannot form. The higher bond orders indicate greater stability for the new molecule.
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Consider a simple example. Hydrogen atoms have one electron in the s shell, and the s shell is capable of holding two electrons. When two hydrogen atoms bond together, each completes the s shell of the other. Two bonding orbitals are formed. No electrons are forced to move to the next higher orbital, the p shell – so no antibonding orbitals are formed. The bonding order is thus , which equals 1. This forms the common molecule H 2 : hydrogen gas. [3] X Research source
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Determine bond order at a glance. A single covalent bond has a bond order of one; a double covalent bond, a bond order of two; a triple covalent bond, three – and so on. [4] X Research source In its most basic form, the bond order is the number of bonded electron pairs that hold two atoms together.- For a more in-depth look, check the periodic table
to see what kind of bonding you've got going on. [5]
X
Expert Source
Chris Hasegawa, PhD
Retired Science Professor & Dean Expert Interview. 29 July 2021.
- For a more in-depth look, check the periodic table
to see what kind of bonding you've got going on. [5]
X
Expert Source
Chris Hasegawa, PhD
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Consider how atoms come together into molecules. In any given molecule, the component atoms are bound together by bonded pairs of electrons. These electrons revolve around the nucleus of an atom in "orbitals," each of which can only hold two electrons. If an orbital is not "full"—i.e., it only holds one electron, or no electrons—then the unpaired electron can bond to a corresponding free electron on another atom.- Depending on the size and complexity of a particular atom, it might have only one orbital, or it might have as many as four.
- When the nearest orbital shell is full, new electrons start to gather in the next orbital shell out from the nucleus, and continue until that shell is also full. The collection of electrons continues in ever-widening orbital shells, as larger atoms have more electrons than smaller atoms. [6] X Research source
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Draw Lewis dot structures . This is a handy way to visualize how the atoms in a molecule are bonded to one another. [7] X Expert Source Chris Hasegawa, PhD
Retired Science Professor & Dean Expert Interview. 29 July 2021. Draw the atoms as their letters (e.g. H for Hydrogen, Cl for Chlorine). Illustrate the bonds between them as lines (e.g. – for a single bond, = for a double bond, and ≡ for a triple bond). Mark the unbonded electrons and electron pairs as dots (e.g. :C:). Once you've drawn your Lewis dot structure, count the number of bonds: this is the bond order.- The Lewis dot structure for diatomic nitrogen would be N≡N. Each nitrogen atom features one electron pair and three unbonded electrons. When two nitrogen atoms meet, their combined six unbonded electrons intermingle into a powerful triple covalent bond. [8] X Research source
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Consult a diagram of electron orbital shells. Note that each shell lies further and further out from the nucleus of the atom. According to the property of entropy, energy always seeks the lowest possible state of order. The electrons will seek to populate the lowest orbital shells available. [9] X Research source -
Know the difference between bonding and antibonding orbitals. When two atoms come together to form a molecule, they seek to use each other's electrons to fill the lowest possible states in the electron orbital shells. Bonding electrons are, essentially the electrons that stick together and fall into the lowest states. Antibonding electrons are the "free" or unbonded electrons that are pushed to higher orbital states. [10] X Research source- Bonding electrons: By noting how full the orbital shells of each atom are, you can determine how many of the electrons in higher energy states will be able to fill the more stable, lower-energy-state shells of the corresponding atom. These "filling electrons" are referred to as bonding electrons.
- Antibonding electrons: When the two atoms try to form a molecule by sharing electrons, some electrons will actually be driven to higher-energy-state orbital shells as the lower-energy-state orbital shells are filled up. These electrons are referred to as antibonding electrons. [11] X Research source
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Expert Q&A
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QuestionHow do you use the periodic table of elements?Dr. Chris Hasegawa was a Science Professor and the Dean at California State University Monterey Bay. Dr. Hasegawa specializes in teaching complex scientific concepts to students. He holds a BS in Biochemistry, a Master’s in Education, and his teaching credential from The University of California, Davis. He earned his PhD in Curriculum and Instruction from The University of Oregon. Before becoming a professor, Dr. Hasegawa conducted biochemical research in Neuropharmacology at the National Institute of Health. He also taught physical and life sciences and served as a teacher and administrator at public schools in California, Oregon, and Arizona.Reference the periodic table to see what type of bonding is going on at different kinds of levels.
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QuestionHow do you visualize different bonds?Dr. Chris Hasegawa was a Science Professor and the Dean at California State University Monterey Bay. Dr. Hasegawa specializes in teaching complex scientific concepts to students. He holds a BS in Biochemistry, a Master’s in Education, and his teaching credential from The University of California, Davis. He earned his PhD in Curriculum and Instruction from The University of Oregon. Before becoming a professor, Dr. Hasegawa conducted biochemical research in Neuropharmacology at the National Institute of Health. He also taught physical and life sciences and served as a teacher and administrator at public schools in California, Oregon, and Arizona.Use the bond's Lewis dot structure as a starting point. You can reference bonding diagrams, too.
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QuestionWhat is the bond order of He2?Community AnswerThe bond order of He2 is 0. It has 2 antibonding electrons and 2 bonding electrons.
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References
- ↑ https://www.khanacademy.org/science/up-class-11-chemistry/xa8e73391a9c6d31a:chemical-bonding-and-molecular-structure/xa8e73391a9c6d31a:untitled-192/v/worked-example-finding-bond-order
- ↑ Chris Hasegawa, PhD. Retired Science Professor & Dean. Expert Interview. 29 July 2021.
- ↑ https://www.researchgate.net/publication/275272738_Calculating_Bond_Orders_and_Their_Significance
- ↑ https://chem.libretexts.org/Bookshelves/Physical_and_Theoretical_Chemistry_Textbook_Maps/Supplemental_Modules_(Physical_and_Theoretical_Chemistry)/Chemical_Bonding/Fundamentals_of_Chemical_Bonding/Bond_Order_and_Lengths
- ↑ Chris Hasegawa, PhD. Retired Science Professor & Dean. Expert Interview. 29 July 2021.
- ↑ https://www.khanacademy.org/science/up-class-11-chemistry/xa8e73391a9c6d31a:chemical-bonding-and-molecular-structure/xa8e73391a9c6d31a:untitled-192/v/worked-example-finding-bond-order
- ↑ Chris Hasegawa, PhD. Retired Science Professor & Dean. Expert Interview. 29 July 2021.
- ↑ https://www.chem.uci.edu/~unicorn/old/H2A/handouts/PDFs/LectureB1.pdf
- ↑ https://www.chem.fsu.edu/chemlab/chm1046course/motheory.html
- ↑ https://scholar.ulethbridge.ca/sites/default/files/susanfindlay/files/chem2000_exercise_3.3_bonding_antibonding_nonbonding.pdf?m=1503437221
- ↑ https://www.khanacademy.org/science/up-class-11-chemistry/xa8e73391a9c6d31a:chemical-bonding-and-molecular-structure/xa8e73391a9c6d31a:untitled-192/v/worked-example-finding-bond-order
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Article Summary
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To calculate bond order in chemistry, subtract the number of the electrons in the antibonding molecules from the number of electrons in the bonding molecules. Divide the result by 2 to get the result. The higher the bond order, the more stable the molecule. To learn how to determine a bond order at a glance, keep reading!
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